Monday, November 17, 2014

Photoluminescent Silicon Nanocrystals with Chlorosilane Surfaces - Synthesis and Reactivity

Nanoscale , 2014, Accepted Manuscript

DOI: 10.1039/C4NR05888G, Communication

Ignaz Malvin Dominik Hohlein, Julian Kehrle, Tapas K Purkait, Jonathan Veinot, Bernhard Rieger

We present a new efficient two-step method to covalently functionalize hydride terminated silicon nanocrystals with nucleophiles. First a reactive chlorosilane layer was formed via diazonium salt initiated hydrosilylation of chlorodimethyl(vinyl)silane...

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